Certain ligand substitution reactions proceed to a complete displacement of the chelate ligand. Certain reactions proceed through a mechanism involving an initial fission of the tungsten-sulfur bond to afford a coordinatively-unsaturated intermediate which is rapidly attacked by chlorobenzene. The resulting solvated intermediate establishes an equilibrium which involves desolvation-solvation. Although main group organometallic chemistry has received a great deal of attention, this discussion will be centered in organotransition metal chemistry, in particular, metal carbonyls.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc330827 |
| Date | 05 1900 |
| Creators | Cortés, José E. (José Enrique) |
| Contributors | Dobson, Gerard R., Thomas, Ruthanne D., Schwartz, Martin, Redding, Rogers W., Conlin, Robert T. |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | xii, 150 leaves : ill., Text |
| Rights | Public, Cortés, José E. (José Enrique), Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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