The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom.
| Identifer | oai:union.ndltd.org:ADTP/275389 |
| Date | January 1967 |
| Creators | Baker, Edward Neill |
| Publisher | ResearchSpace@Auckland |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated., http://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm, Copyright: The author |
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