Pauling (1931) introduced the concept of the hybridisation of (n - 1)d, ns and np orbitals to explain the two classes 'ionic' and 'covalent' into which co-ordination compounds of transition metals appeared to fall. These two classes in general have different numbers of unpaired spins, hence they will be distinguished by their magnetic moments. For a series of ferric salts a moment corresponding to either one or five unpaired spins was found, but not intermediate values. I the 'ionic' case the five d-electrons go into the 3d orbitals with their spins parallel giving a moment corresponding to five unpaired spins. I the octahedral case d2 sp3 hybridisation occurs, leaving three d-orbitals to hours the five d-electrons thus giving rise to a moment corresponding to one unpaired spin.
Identifer | oai:union.ndltd.org:ADTP/276064 |
Date | January 1960 |
Creators | Waters, Joyce Mary Partridge |
Publisher | ResearchSpace@Auckland |
Source Sets | Australiasian Digital Theses Program |
Language | English |
Detected Language | English |
Rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated., http://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm, Copyright: The author |
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