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Syntheses, structures and reactivities of bis(thiophosphinoyl) metal complexes.

Wan, Chi Ling. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.vi / Acknowledgement --- p.i / Abstract --- p.ii / 摘要 --- p.iv / List of Compounds Synthesized in This Work --- p.x / Abbreviation --- p.xi / Chapter Chapter 1 --- Synthesis of Group 1 and 2 Metal Bis(thiophosphinoyl) Complexes / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.1.1 --- General Aspects of Thiophosphinoyl Ligands --- p.1 / Chapter 1.1.2 --- General Aspects of Group 1 and 2 Thiophosphinoyl Metal Complexes --- p.6 / Chapter 1.1.3 --- Objectives of This Work --- p.10 / Chapter 1.2 --- Results and Discussion --- p.11 / Chapter 1.2.1.1 --- Synthesis of Monoanionic Bis(thiophosphinoyl) Lithium Complex --- p.11 / Chapter 1.2.1.2 --- Spectroscopic Properties of 42 --- p.11 / Chapter 1.2.1.3 --- Molecular Structure of [Li{(S=PPh2)CH}(THF)(Et20)] (42) --- p.12 / Chapter 1.2.2.1 --- Synthesis of Dianionic Bis(thiophosphinoyl) Magnesium Complex --- p.14 / Chapter 1.2.2.2 --- Spectroscopic Properties of 43 --- p.14 / Chapter 1.2.2.3 --- Molecular Structure of [MgC(PPh2=S)(THF)]2.2THF (43) --- p.15 / Chapter 1.3 --- Experimental for Chapter 1 --- p.17 / Chapter 1.4 --- References for Chapter 1 --- p.19 / Chapter Chapter 2 --- Synthesis and Reactivity of Group 14 Metal Bis(thiophosphinoyl) Complexes / Chapter 2.1 --- Introduction --- p.24 / Chapter 2.1.1 --- General Aspects of Low Valent Group 14 Organometallic Compounds --- p.24 / Chapter 2.2 --- Results and Discussion --- p.32 / Chapter 2.2.1.1 --- "Synthesis of 1,3-Distannacyclobutane and 1,3-Diplumbacyclobutane" --- p.32 / Chapter 2.2.1.2 --- Spectroscopic Properties of 74 and 75 --- p.33 / Chapter 2.2.1.3 --- Molecular Structures of [Sn{u2-C(Ph2P=S)2}]2.THF (74) and [Pb{u2-C(Ph2P=S)2}]2.THF(75) --- p.34 / Chapter 2.2.2.1 --- "Reaction of 1,3-Diplumbacyclobutane with Chalcogens" --- p.38 / Chapter 2.2.2.2 --- Spectroscopic Properties of 78 and 79 --- p.39 / Chapter 2.2.2.3 --- "Molecular Structures of [PbE{C(PPh2=S)2}] (E = S (78),Se (79))" --- p.39 / Chapter 2.2.3.1 --- Synthesis of Chlorogermylene and Chlorostannylene --- p.44 / Chapter 2.2.3.2 --- Spectroscopic Properties of 80 and 81 --- p.44 / Chapter 2.2.3.3 --- "Molecular Structures of [MCl{CH(PPh2=S)2}] (M = Ge (80),Sn (81))" --- p.45 / Chapter 2.2.4.1 --- Reaction of Chlorogermylene with Chalcogens --- p.49 / Chapter 2.2.4.2 --- Spectroscopic Properties of 82 --- p.50 / Chapter 2.2.4.3 --- Molecular Structure of [GeCl{CH(PPh2=S)2}(u-S)]2.4THF (82) --- p.51 / Chapter 2.2.4.4 --- Reaction of Chlorostannylene with Pb{N(SiMe3)2}2 --- p.53 / Chapter 2.3 --- Experimental for Chapter 2 --- p.54 / Chapter 2.4 --- References for Chapter 2 --- p.60 / Chapter Chapter 3 --- Synthesis of Group 13 Metal Bis(thiophosphinoyl) Complexes / Chapter 3.1 --- Introduction --- p.65 / Chapter 3.1.1 --- General Aspects of Group 13 Organometallic Chemistry --- p.65 / Chapter 3.1.2 --- General Aspects of Group 13 Metal Complexes Bearing Phosphoranoimine or Phosphoranosulfide Ligands --- p.67 / Chapter 3.2 --- Results and Discussions --- p.72 / Chapter 3.2.1 --- Synthesis of Group 13 Metal Bis(thiophosphinoyl) Complexes --- p.72 / Chapter 3.2.2 --- Spectroscopic Properties of 108-110 --- p.72 / Chapter 3.2.3 --- "Molecular Structures of [MCl{C(PPh2=S)2}]2 (M = A1 (108),Ga (109), In (110))" --- p.73 / Chapter 3.3 --- Experimental for Chapter 3 --- p.79 / Chapter 3.4 --- References for Chapter 3 --- p.82 / Chapter Chapter 4 --- Synthesis of Group 4 Metal Bis(thiophosphinoyl) Complexes / Chapter 4.1 --- Introduction --- p.86 / Chapter 4.1.1 --- General Aspects of Group 4 Early Transition Metal Complexes --- p.86 / Chapter 4.2 --- Results and Discussion --- p.92 / Chapter 4.2.1 --- Synthesis of Group 4 Metal Bis(thiophosphinoyl) Complexes --- p.92 / Chapter 4.2.2 --- Spectroscopic Properties of 125-128 --- p.93 / Chapter 4.2.3 --- Molecular Structures of [Hf(NMe2)3{CH(PPh2=S)2}] (126) --- p.94 / Chapter 4.3 --- Experimental for Chapter 4 --- p.97 / Chapter 4.4 --- References for Chapter 4 --- p.100 / Appendix I / Chapter A. --- General Procedures --- p.104 / Chapter B. --- Physical and Analytical Measurements --- p.104 / Chapter C. --- X-ray Crystallographic Determination --- p.105 / Appendix II / "Table A.1. Selected Crystallographic Data for Compounds 42,43,74 and 75" --- p.108 / Table A.2. Selected Crystallographic Data for Compounds 77-80 --- p.109 / "Table A.3. Selected Crystallographic Data for Compounds 81,108-110 and 126" --- p.110 / Appendix III / Chapter A. --- Future Work --- p.111

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326777
Date January 2009
ContributorsWan, Chi Ling., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xii, 113 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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