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Structures of Werner clathrates

Includes bibliographical references. / X-ray crystallographic studies have been used to elucidate the structures of two new Werner clathrates. ... The chloroform molecule is disordered, lying on a two-fold axis. Stoicheiometric characterization of the clathrates was determined using various chemical techniques, including mass spectroscopy, proton nuclear magnetic resonance and complex iometric titration. The clathrating phase of the second clathrate was investigated by guest-loss studies on a McBain balance followed by X-ray powder photography. Host-quest non-bonded interactions of both clathrate compounds were studied using atom-pair potentials.

Identiferoai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uct/oai:localhost:11427/15811
Date January 1983
CreatorsPapanicolaou, Sevasti
ContributorsNassimbeni, Luigi R
PublisherUniversity of Cape Town, Faculty of Science, Department of Chemistry
Source SetsSouth African National ETD Portal
LanguageEnglish
Detected LanguageEnglish
TypeDoctoral Thesis, Doctoral, PhD
Formatapplication/pdf

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