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Thermal and compositional variation of glassy metal structure factors

The x-ray total structure factor of the glassy-metal alloys $Mg sb{70}Zn sb{30}, Ca sb{70}Mg sb{30}$ and $Mg sb{85.5}Cu sb{14.5}$ has been measured at three temperatures: 9K, 150K, and 300K. The data have a statistical precision of about.8% and an absolute accuracy of roughly 3%. / Percus-Yevick hard sphere structure factors may be fitted quite accurately to the data in the region of the first peak. In addition, the variation of the experimental structure factor with composition is found to be consistent with the Percus-Yevick theory. At low k values, Percus-Yevick and other theoretical model structure factors are in poor agreement with the data. / Within experimental error, the temperature dependence of the structure factors is in agreement with the Debye plane wave phonon model of atomic vibrations. / The measured structure factors are used to calculate the electrical resistivity from the Faber-Ziman equation. In most cases, the calculations yield both the correct magnitude of resistivity and sign of the temperature coefficient of resistivity.

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.74302
Date January 1989
CreatorsFrom, Milton
PublisherMcGill University
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Formatapplication/pdf
CoverageDoctor of Philosophy (Department of Physics.)
RightsAll items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
Relationalephsysno: 001066244, proquestno: AAINN63554, Theses scanned by UMI/ProQuest.

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