This thesis reports the synthesis and characterization of two new copper(II) halide complexes with deprotonated N-(2-hydroxyethyl)ethylenediamine behaving as a bidentate. The magnetic properties of the new copper(II) complexes were studied from room temperature to liquid nitrogen temperatures. The magnetic data show that both complexes exhibit antiferromagnetic interactions with a singlet ground state and a thermally accessible triplet excited state. Magnetic data and infrared spectra indicate the complexes are halogenbridged. Deprotonation at an amine nitrogen is based on the presence of a hydroxyl stretching band in the infrared spectra. Electronic spectra and infrared spectra indicate the complexes are square planar. Elemental analyses, infrared spectra, electronic spectra, electron spin resonance spectra, and magnetic data are reported and discussed.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc663729 |
| Date | 12 1900 |
| Creators | Miller, Toney G. |
| Contributors | Theriot, L. J., Russell, Benny |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vi, 57 leaves: ill., Text |
| Rights | Public, Miller, Toney G., Copyright, Copyright is held by the author, unless otherwise noted. All rights |
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