Isobutylene-rich elastomers bearing functional groups that engage N-arylmaleimides in C-H bond addition and/or alternating copolymerization are described. While inactive to cross-linking when treated at high temperature with peroxide alone, these co-curing elastomers can be cross-linked substantially when combined with bis-maleimide coagents such as N,N’-m-phenylene dimaleimide (BMI). Poly(isobutylene-co-isoprene) (IIR) samples containing relatively high amounts of residual isoprene unsaturation are shown to provide relatively low coagent cure reactivity, whereas IIR derivatives bearing pendant polyether or vinyl ether functionality are shown to provide exceptional cross-linking rates and extents when treated with identical BMI formulations. The design of such co-curing elastomers is discussed, along with the physical properties of the resulting vulcanizates.
Isobutylene rich elastomers bearing oligomerizable (C=C) functional groups, macromonomers, that are activated in the presence of free-radical initiators are described. The criteria for determining the macromonomers that are best suited for preparing thermosets of IIR is discussed. While IIR derivatives bearing pendant acrylic, styrenic and maleimide functionality are shown to provide exceptional cross-linking rates and extents, they are also shown to suffer from instability in the absence of peroxide. IIR carrying pendant methacrylic and itaconate functionality are shown to provide a good balance of cure rates and stability. Nitroxyl based radical trap that provides scorch protection to the macromonomers while regenerating the cure extent is discussed.
Functional macromonomer derivatives of IIR bearing containing multi-functional pendant groups are discussed. IIR derivatives with itaconate and low amounts of BHT pendant groups is shown to act as bound anti-oxidant while IIR containing pendant fluoro groups are shown to have reduced surface energy. Ionic coagents are used to cross-link IIR containing itaconate pendant groups and their physical properties are discussed. / Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2012-07-06 11:20:56.915
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OKQ.1974/7314 |
| Date | 06 July 2012 |
| Creators | Siva Shanmugam, Karthik Vikram |
| Contributors | Queen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.)) |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English, English |
| Detected Language | English |
| Type | Thesis |
| Rights | This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. |
| Relation | Canadian theses |
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