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Macrocyclic polyether sulfide syntheses :|bthe preparation of thia-crown-6, 7, and 8 compounds

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol in refluxing basic ethanol. The following new compounds were prepared: 1,5-dithia-(19- crown-6), 3-hydroxy-1,5-dithia-(19-crown-6), 1,4-dithia-(21-crown-7), 3-hydroxy-1,5-dithia-(22-crown-7), and 1,4-dithia-(24-crown-8). One other previously reported macrocyclic polyether sulfide was also prepared. The thesis includes a review of macrocyclic sulfides and other related compounds, the thermodynamics of interaction of several macrocyclic polyether sulfides with Ag^+, Hg^2+, and Pb^2+ ions, and a discussion of the structure of these materials.

Identiferoai:union.ndltd.org:BGMYU2/oai:scholarsarchive.byu.edu:etd-9336
Date01 August 1975
CreatorsReeder, Robert Askew
PublisherBYU ScholarsArchive
Source SetsBrigham Young University
Detected LanguageEnglish
Typetext
Formatapplication/pdf
SourceTheses and Dissertations
Rightshttp://lib.byu.edu/about/copyright/

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