Chan, Wing Shong Thierry. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references (leaves 82-88). / Abstract also in Chinese. / Contents --- p.i / Acknowledgments --- p.iii / Abstract --- p.iv / Abbreviations --- p.vi / Chapter Chapter 1 - --- Dendronized Polymers and Supramolecular Polymers --- p.1 / Chapter 1.1 --- Introduction to Dendrons and Dendrimers --- p.1 / Chapter 1.2 --- Dendronized polymers --- p.4 / Chapter 1.2.1 --- Graft-from Method --- p.5 / Chapter 1.2.2 --- Graft-to Method --- p.7 / Chapter 1.2.3 --- Macromonomer Method --- p.8 / Chapter 1.2.3.1 --- Step Growth Polymerization --- p.9 / Chapter 1.2.3.2 --- Chain Growth Polymerization --- p.10 / Chapter 1.2.3.3 --- Living Chain Growth Polymerization --- p.11 / Chapter 1.3 --- Supramolecular Polymers --- p.12 / Chapter 1.4 --- Supramolecular Dendronized Polymers --- p.13 / Chapter Chapter 2 - --- Design of Supramolecular Dendronized Polymers --- p.18 / Chapter 2.1 --- Hydrogen Bonding --- p.19 / Chapter 2.1.1 --- Binary Characters of Hydrogen Bonding --- p.20 / Chapter 2.2 --- 2-Ureido-4[ 1H]-Pyrimidinone (UPy) --- p.22 / Chapter 2.3 --- Effects of Dendrons on Dimerization Constant of UPy --- p.25 / Chapter 2.4 --- Target Supramolecular Dendronized Polymers --- p.26 / Chapter Chapter 3 - --- Synthesis and Characterization of Supramolecular Dendronized Polymers --- p.28 / Chapter 3.1 --- Retro-Synthesis --- p.28 / Chapter 3.2 --- Synthesis of [G1]-[G3] Bifunctional Protected Monomers --- p.28 / Chapter 3.3 --- Characterization of Intermediates --- p.34 / Chapter 3.3.1 --- 1H NMR Spectroscopy --- p.34 / Chapter 3.3.2 --- 13C NMR Spectroscopy --- p.37 / Chapter 3.3.3 --- Mass Spectroscopy --- p.40 / Chapter 3.3.4 --- Size Exclusion Chromatography (SEC) --- p.40 / Chapter 3.4 --- Deprotection of [G1]-[G3] Biflmctional O-benzyl Protected Monomers --- p.41 / Chapter 3.5 --- Characterization of [G1]´ؤ[G3] Bifunctional Dendronized Monomers --- p.44 / Chapter 3.5.1 --- Characterization of [G1] Dendronized Di-UPy Monomer --- p.44 / Chapter 3.5.2 --- Characterization of [G2] Dendronized Di-UPy Monomer --- p.46 / Chapter 3.5.3 --- Characterization of [G3] Supramolecular Dendronized Di-Upy Polymer --- p.47 / Chapter 3.6 --- Conclusion --- p.49 / Chapter Chapter 4 - --- Properties of Supramolecular Dendronized Polymers --- p.50 / Chapter 4.1 --- Viscosity Measurement --- p.50 / Chapter 4.1.1 --- Introduction --- p.51 / Chapter 4.1.2 --- Viscosity Result At Room Temperature --- p.52 / Chapter 4.1.3 --- Viscosity Result At Different Temperatures --- p.53 / Chapter 4.1.4 --- Viscosity Result In Different Solvents --- p.55 / Chapter 4.2 --- Proton NMR --- p.56 / Chapter 4.3 --- Scanning Electron Microscopy --- p.59 / Chapter 4.4 --- Gelation Property --- p.61 / Chapter 4.5 --- Conclusion --- p.63 / Chapter Chapter 5 - --- Experimental Procedures --- p.66 / Chapter 5.1 --- General Information --- p.66 / Chapter 5.2 --- Experimental Procedures --- p.67 / References --- p.82 / NMR spectra --- p.89
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326861 |
| Date | January 2009 |
| Contributors | Chan, Wing Shong Thierry., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, vii, 133 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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