The apparent integral diffusion coefficients of ceric sulphate solutions, 4 normal in sulphuric acid, were measured for concentrations ranging from 0.05 normal to 0.415 normal at 25°C with the use of a pyrex sintered glass diaphragm diffusion cell. A graph obtained by plotting the calculated integral diffusion coefficients versus the square root of the initial concentration is similar to the graphs obtained for uni-univalent salts. The rate of diffusion, however, is less by a factor of ten. The sintered glass diaphragm cell was calibrated with 0.1 normal potassium chloride at 25°C and the value of the cell constant was determined to be 0.1111 ± 0.0002 cm⁻². / Science, Faculty of / Chemistry, Department of / Graduate
Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/41327 |
Date | January 1951 |
Creators | McFadden, Mary Louise |
Publisher | University of British Columbia |
Source Sets | University of British Columbia |
Language | English |
Detected Language | English |
Type | Text, Thesis/Dissertation |
Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
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