Xenobiotic compounds, which are exclusively man made, are produced in large quantities every year and released to the environment. Besides, anaerobic sludge digestion offers advantage in co-treatment of hazardous substances produced by the industry. The performance of the digesters can be monitored by modeling efforts. In this study, Anaerobic Digestion Model No.1 (ADM1) was calibrated, and validated for full-scale digester, lab-scale digester, and lab-scale digester seeded with totally different anaerobic biomass than that of full-scale digester. The model xenobiotic compound, a mono azo dye RO107, was co-treated with sewage sludge in an anaerobic digester. High removal efficiencies as 98% was found for azo dye at standard operating conditions of anaerobic digesters. The digester performance was not effected from azo dye or its reduction products. The dye reduction mechanism was modeled by biochemical mechanism due to unspecific enzymes and by chemical mechanism due to sulfide reduction. Some of the dye metabolites were suggested to be degraded by aerobic biotreatment. The anaerobic reduction metabolites of RO107 were identified as 2-(4-aminophenylsulfonyl) ethanol and 2,5-diamino-4-formamidobenzenesulfonic acid, and sulfanilic acid.
| Identifer | oai:union.ndltd.org:METU/oai:etd.lib.metu.edu.tr:http://etd.lib.metu.edu.tr/upload/3/12609952/index.pdf |
| Date | 01 September 2008 |
| Creators | Ozkan Yucel, Umay G. |
| Contributors | Gokcay, Celal F. |
| Publisher | METU |
| Source Sets | Middle East Technical Univ. |
| Language | English |
| Detected Language | English |
| Type | Ph.D. Thesis |
| Format | text/pdf |
| Rights | To liberate the content for public access |
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