The value of the dipole moment ,μ, of NH in the A³π state was found to be 1.31 ± .03 Debye. This value was
determined from data on the Stark effect measured from
spectrograms of the A³π- X³Σ-, 3360 Å, band taken on a
3.4 meter grating spectrograph in third order giving a resolution of about 100,000. The theory of the Stark
effect in molecules was taken from papers by W. G. Penny5
and Van Vleck and Hill9 . The magnitude of the electric field was determined from the Stark splitting of the hydrogen line Hβ according to the theory given in The Theory of Atomic Spectra6 . In the near future I should be able to complete work on the c’π→a’Δ, 3240 Å, band and give the values of the dipole moments for states c and a as well. Thus it will be possible to determine how the dipole moment changes with electronic configuration. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/38467 |
| Date | January 1965 |
| Creators | Irwin, Timothy Alexander Ready |
| Publisher | University of British Columbia |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
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