The Toarcian, Early Jurassic, Oceanic Anoxic Event (T-OAE: ~183 Ma) was characterized by globally synchronous deposition of sediments rich in organic carbon (black shales), and is associated with an abrupt negative carbon isotope excursion, disrupting a positive carbon-isotope excursion during the tenuicostatum–serpentinum ammonite Zone boundary. The T-OAE has been extensively studied in northern and southern Europe, but evidence from the southern hemisphere is limited. New geochemical data from the tenuicostatum–hoelderi (~serpentinum) Andean ammonite Zone, from the Neuquén Basin, Argentina provides evidence for the global imprint of the event. The event is recorded in bulk-sediment from Arroyo Lapa (North and South) and Arroyo Serrucho with δ<sup>13</sup>C<sub>org</sub> values of -30‰ – -32.5‰ and δ<sup>13</sup>C values from fossil wood fall to -30.7 ‰, isotopic ratios that are comparable to those identified in Europe for the T-OAE. Hydrogen Index (HI) data for the T-OAE in Argentina give values ranging from 12 to 425 mg HC/ g TOC, indicating a mixture of terrestrial and marine organic components. Pristane/Phytane ratios and pyrite framboid distribution data indicative of anoxic conditions occur at some levels, and new δ<sup>98/95</sup>Mo data, with values ranging from ~ -0.2 to 0.78 ‰, which contrast with previously published molybdenum-isotope values from T-OAE black shales of northern Europe. Sedimentological data also reveals a marine transgression during the tenuicostatum–hoelderi Andean ammonite zone.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:568064 |
| Date | January 2011 |
| Creators | Al-Suwaidi, Aisha H. |
| Contributors | Hesselbo, Stephen P. ; Jenkyns, Hugh |
| Publisher | University of Oxford |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | http://ora.ox.ac.uk/objects/uuid:4245fc05-416a-41c4-86ea-851005eca605 |
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