Precision measurements of the Mössbauer fraction of the 14.4 kev Fe⁵⁷ transition were made using the black, wide absorber technique. The Fe⁵⁷ was diffused, as a dilute Mössbauer impurity, into 99.995% purity single crystal chips of Pt, Pd and Cu. By comparing the Debye form of -ln f, corrected for anharmonicity, with our data, we extracted a high and low temperature Debye theta, as well as an anharmonicity coefficient, є, for the three materials. We estimated the accuracy of our data to be ± 1%. From the data we concluded that the Fe⁵⁷ in Cu has stronger force constants and is more anharmonic than pure Cu, while Fe⁵⁷ in Pt and Pd has smaller force constants and about the same anharmonicity as the pure host materials.
| Identifer | oai:union.ndltd.org:pdx.edu/oai:pdxscholar.library.pdx.edu:open_access_etds-1016 |
| Date | 01 June 1968 |
| Creators | Nees, Wilbur Lee |
| Publisher | PDXScholar |
| Source Sets | Portland State University |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | Dissertations and Theses |
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