This thesis investigates the possibility of using electrokinetic effects, induced when a colloidal system is subjected to an electric field, to produce deterministic structure in the catalyst layer of polymer electrolyte membrane fuel cells. The susceptibility of the catalyst ink system to electrokinetic effects is clearly demonstrated. A novel apparatus and procedure is developed to allow for the formation of continuous films between two electrode surfaces through solvent evaporation. Characterization of the resulting layers is done through imaging and rotating disc electrode measurements. While the images show some possibility of structure formation, no clear increase in the oxygen reduction rate is observed. Recommendations for extending this work are provided. / Thesis (Master, Chemical Engineering) -- Queen's University, 2010-01-06 17:29:23.27
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OKQ.1974/6903 |
| Date | 12 December 2011 |
| Creators | Hoidas, MARK |
| Contributors | Queen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.)) |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English, English |
| Detected Language | English |
| Type | Thesis |
| Rights | This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. |
| Relation | Canadian theses |
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