Electrically conductive fabrics are one of the major components of smart textile that attracts a lot of attention by the energy, medical, sports and military industry. The principal contributors to the conductivity of the smart textiles are the intrinsic properties of the fiber, functionalization by the addition of conductive particles and the architecture of fibers. In this study, intrinsic properties of non-woven carbon fabric derived from a novel linear lignin, poly-(caffeyl alcohol) (PCFA) discovered in the seeds of the vanilla orchid (Vanilla planifolia) was investigated. In contrast to all known lignins which comprise of polyaromatic networks, the PCFA lignin is a linear polymer. The non-woven fabric was prepared using electrospinning technique, which follows by stabilization and carbonization steps. Results from Raman spectroscopy indicate higher graphitic structure for PCFA carbon as compared to the Kraft lignin, as seen from G/D ratios of 1.92 vs 1.15 which was supported by a high percentage of graphitic (C-C) bond observed from X-ray photoelectron spectroscopy (XPS). Moreover, from the XRD and TEM a larger crystal size (Lc=12.2 nm) for the PCFA fiber was obtained which correlates to the higher modulus and conductivity of the fiber. These plant-sourced carbon fabrics have a valuable impact on zero carbon footprint materials. In order to improve the strength and flexibility of the non-woven carbon fabric, lignin was blended with the synthetic polymer Poly acrylonitrile (PAN) in different concertation, resulting in electrical conductivity up to (7.7 S/cm) on blend composition which is enough for sensing and EMI shielding applications. Next, the design of experiments approach was used to identify the contribution of the carbonization parameters on the conductivity of the fabrics and architecture of the fibers, results show carbonization temperature as the major contributing factor to the conductivity of non-woven fabric. Finally, a manufacturing procedure was develop inspired by the architecture of plant fibers to induce controlled porosity either on the skin or core of fibers which results in stiffness and flexibility in the fibers. Coaxial Electrospinning and Physical foaming (CO2 foaming) techniques were utilized to create the hierarchical fiber architecture. Finite Element model was developed to design for mechanical properties of the bioinspired fiber mesh. Results show the polymers contributes less in a coaxial design as compared to the individual fibers for mechanical properties. This manufacturing method can use for hierarchical functionalization of fibers by adding conductive nanoparticles at different levels of fiber cross-section utilized for sensing applications in sports and medical industry.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc1062837 |
| Date | 08 1900 |
| Creators | Rizvi, Syed Hussain Raza |
| Contributors | D'Souza, Nandika, Shi, Sheldon, Vaidyanathan, Vijay, Li, Xiaohua, Heo, Hyeonu |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | x, 139 pages, Text |
| Rights | Public, Rizvi, Syed Hussain Raza, Copyright, Copyright is held by the author, unless otherwise noted. All rights Reserved. |
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