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Synthesis and properties of enantiopure planar chiral poly(p-phenylenevinylene)s.

Mo Kai For. / Thesis submitted in: November 2001. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 78-81). / Abstracts in English and Chinese. / Contents --- p.i / Acknowledgement --- p.iii / Abstract --- p.iv / Chapter I --- Introduction --- p.1 / Chapter II --- Results and Discussion --- p.14 / Chapter II.1 --- Synthesis of racemic planar chiral PPV by bimolecular polymerization using the Horner-Emmons-Wadsworth reaction --- p.14 / Chapter II.2 --- Formation of racemic [n]paracyclophane-based homo-PPVs from rac- bis(chloromethyl)[n]paracyclophanes by the Gilch reaction --- p.17 / Chapter II.3 --- Preparation of enantiopure bis(halomethyl)[n]paracyclophanes to be used as monomers for the synthesis of planar chiral non-racemic PPVs --- p.21 / Chapter II.4 --- Synthesis of [ 14] [ 14]metaparacyclophane ´ؤthe first example of a [m] [n]metaparacyclophane --- p.24 / Chapter II.5 --- Synthesis of enantiopure [n]paracyclophane-based homo-PPVs from enantiopure bis(bromomethyl)[n]paracyclophanes by the Gilch reaction --- p.29 / Chapter II.6 --- "Copolymers formation from enantiopure bis(bromomethyl)[n]paracyclophanes and racemic α,α'-dibromo-2,5-bis(3,7-dimethyloctyloxy)-p-xylene by the Gilch reaction" --- p.32 / Chapter II.7 --- "Characterization of the chiral non-racemic poly[(pR/pS)-[n]-2,5-paracyclo-1,4- phanylene-(E)-vinylene]-co-[2,5-bis(3,7-dimethyloctyloxy)-l,4-phenylene- (E)-vinylene] polymers" --- p.35 / Chapter III --- Conclusion --- p.53 / Chapter IV --- Experimental --- p.54 / References --- p.78 / Spectra --- p.82

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_324014
Date January 2002
ContributorsMo, Kai For., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, v, 100 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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