The threshold potentials were determined for the excitation energy necessary for low energy electrons to induce chemical reactions of carbon monoxide, and of nitric oxide adsorbed on a gold surface. The reactions were studied as a function of temperature (100 °C to 200 °C) and pressure (1.83 x 10-5 to 6.40 x 10-4 torr). The electron source was a thorium oxide coated iridium filament which was heated by a current between 1A and 3A to keep thermal distribution of the electrons to less than 0.4 ev. The reaction surface was a polycrystalline evaporated film prepared by subliming gold onto a stainless steel mesh support. Mass analysis was done by quadrupole mass spectrometry in a flow system.
The general results of the research is that a technique has been developed to study the products of reactions of excited state atoms or molecules on metal surfaces. The electron-impact excitation method is an alternative to photochemical and other methods.
| Identifer | oai:union.ndltd.org:pacific.edu/oai:scholarlycommons.pacific.edu:uop_etds-3175 |
| Date | 01 January 1989 |
| Creators | St. Denis, Michael Joseph |
| Publisher | Scholarly Commons |
| Source Sets | University of the Pacific |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | University of the Pacific Theses and Dissertations |
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