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Synthesis and Studies of AzaBODIPY Derived Donor-Acceptor Systems for Light Induced Charge Separation

The efficiency and mechanism of electron- and energy transfer events occurring in both in natural and synthetic donor-acceptor systems depend on their distance, relative orientation, and the nature of the surrounding media. Fundamental knowledge gained from model studies is key in building efficient energy harvesting and optoelectronic devices. Faster charge separation and slower charge recombination in donor-acceptor systems is often sought out. In our continued effort to build donor-acceptor systems using near-IR sensitizers, in the present study, we report ground and excited state charge transfer in newly synthesized, directly linked, tetrads featuring bisdonor (donor = phenothiazine and ferrocene), BF2-chelated azadipyrromethane (azaBODIPY) and C60 entities. The tetrads synthesized using multi-step synthetic procedure revealed strong charge transfer interactions in the ground state involving the donor and azaBODIPY entities. The near-IR emitting azaBODIPY acted as a photosensitizing electron acceptor along with fullerene while the phenothiazine and ferrocene entities acted as electron donors. The triads (bisdonor-azaBODIPY) and tetrads revealed ultrafast photoinduced charge separation leading to D•+-azaBODIPY•–-C60 and D•+-azaBODIPY-C60•– (D = phenothiazine or ferrocene) charge separated states from the femtosecond transient absorption spectral studies in both polar and nonpolar solvent media. The charge separated states populated the triplet excited state of azaBODIPY prior returning to the ground state.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc1404570
Date12 1900
CreatorsCollini, Melissa A.
ContributorsD'Souza, Francis, Omar, Mohammad, Dandekar, Sushama
PublisherUniversity of North Texas
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatviii, 59 pages, Text
RightsPublic, Collini, Melissa A., Copyright, Copyright is held by the author, unless otherwise noted. All rights Reserved.

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