Chemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding contaminant fate and transport. This work explored the effects of soil structure (i.e. layers, lenses) on linked geochemical, hydrological, and microbiological processes under changing hydrologic conditions (e.g. rainfall, introduction of groundwater, and fluctuating water table heights). A homogenized medium-grained sand, homogenized organic-rich loam and a sand-over-loam layered column were constructed for the first series of experiments. The second series of experiments employed two soil columns with lenses that were packed identically with sterilized and untreated sediments. Each consisted of two lenses of organic-rich loam in a medium-grained sand matrix. Lenses were located at different vertical depths and were horizontally offset. In-situ collocated probes collected soil hydrologic and chemical data.
In the layered column, enhanced biogeochemical cycling was observed over the texturally homogeneous soil columns. Enumerations of Fe(III) and SO42- reducing microorganisms also show 1-2 orders of magnitude greater community numbers in the layered column. The greatest concentrations of aqueous FeS clusters (FeSaq) were observed in close proximity to the soil interface. To our knowledge, this was the first documentation of FeSaq in partially saturated sediments. Mineral and soil aggregate composite layers were also most abundant near the soil layer interface; the presence of which, likely contributed to an order of magnitude decrease of hydraulic conductivity.
In the live lens column, Fe-oxide bands formed at the fringes of the lenses that retarded water flow rates by an order of magnitude compared to the sterilized column. Microbial activity also produced insoluble gases and that led to the creation of a separate gas phase that reduced hydraulic conductivity. This limited the interaction between groundwater with soil-pore waters that led to the formation of geochemically distinct water masses in relatively close proximity to one another. No such changes were observed in the sterilized column.
When compared to homogenous columns, the presence of soil heterogeneities altered biogeochemical and hydrologic processes considerably which highlights the need to consider soil heterogeneity in contaminant fate and transport models. These findings suggest that quantifying coupled hydrologic-biogeochemical processes occurring at small scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale.
| Identifer | oai:union.ndltd.org:tamu.edu/oai:repository.tamu.edu:1969.1/ETD-TAMU-2011-08-9784 |
| Date | 2011 August 1900 |
| Creators | Hansen, David Joseph |
| Contributors | McGuire, Jennifer T., Mohanty, Binayak P. |
| Source Sets | Texas A and M University |
| Language | en_US |
| Detected Language | English |
| Type | thesis, text |
| Format | application/pdf |
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