EN The thesis is focused on a speciation analysis of arsenic with use of the hydride generation - cryotrapping - gas chromatography - atomic absorption spectrometry. The aim of this project was the development of a method and instrumentation of the speciation analysis of arsenic based on combination of selective generation of substituted hydrides with a detection by atomic absorption spectrometry and with use of the cryotrapping of generated arsenic species and their separation by the gas chromatography. In the first part of this work the effects of individual parameters which influence the separation in the gas chromatograph were studied. Especially, time of injection from the cryotrap into GC, temperature program, carrier gas flow and carrier gas flow through a "deanswitch". Optimization of these parameters is an attempt to achieve a satisfactory resolution of the individual peaks of arsenic species separated by gas chromatography. Furthermore, an adequate sensitivity of this method is required to be achieved in comparison to other methods that use AAS detection such as a combination of hydride generation with cryotrapping. For this reason, the detection limits and the quantification of arsenic species were important to be determined as well. A sampling coil was replaced by a sampling tip...
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:380273 |
| Date | January 2018 |
| Creators | Petreňová, Štěpánka |
| Contributors | Svoboda, Milan, Šucmanová, Marcela |
| Source Sets | Czech ETDs |
| Language | Slovak |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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