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A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses

This paper summarizes a recently developed continuum theory for the elastic-viscoplastic deformation of amorphous solids such as polymeric and metallic glasses. Introducing an internal-state variable that represents the local free-volume associated with certain metastable states, we are able to capture the highly non-linear stress-strain behavior that precedes the yield-peak and gives rise to post-yield strain-softening. Our theory explicitly accounts for the dependence of the Helmholtz free energy on the plastic deformation in a thermodynamically consistent manner. This dependence leads directly to a backstress in the underlying flow rule, and allows us to model the rapid strain-hardening response after the initial yield-drop in monotonic deformations, as well as the Bauschinger-type reverse-yielding phenomena typically observed in amorphous polymeric solids upon unloading after large plastic deformations. We have implemented a special set of constitutive equations resulting from the general theory in a finite-element computer program. Using this finite-element program, we apply the specialized equations to model the large-deformation response of the amorphous polymeric solid polycarbonate, at ambient temperature and pressure. We show numerical results to some representative problems, and compare them against corresponding results from physical experiments. / Singapore-MIT Alliance (SMA)

Identiferoai:union.ndltd.org:MIT/oai:dspace.mit.edu:1721.1/3660
Date01 1900
CreatorsAnand, Lallit
Source SetsM.I.T. Theses and Dissertation
Languageen_US
Detected LanguageEnglish
TypeArticle
Format211086 bytes, application/pdf
RelationAdvanced Materials for Micro- and Nano-Systems (AMMNS);

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