The Onsager heat of transport, Q*, has been measured for water vapour above glycerol-water solutions (75 % to 94.5 % glycerol) over a temperature range of -46 to -32 ℃. For solutions of concentrations 80 % and above, Q* varied from 5.41 kJ mol-1 ± 0.97 to 17.37 kJ mol-1 ± 2.61, consistent with previous results for aniline and n-heptanol. The dissociation of glycerol-water complexes was not rate determining, as was the case for sulfuric acid-water solutions, and therefore the glycerol-water system is a better two component system analog for comparison with the CO2-water system than the sulfuric acid-water system.
| Identifer | oai:union.ndltd.org:ADTP/273746 |
| Date | January 2007 |
| Creators | James, Ronald Arthur |
| Publisher | University of Canterbury. Chemistry |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | Copyright Ronald Arthur James, http://library.canterbury.ac.nz/thesis/etheses_copyright.shtml |
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