Yeung, Lai Fong. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references (leaves 122-124). / Abstracts in English and Chinese. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgement Contents --- p.iv / Abbreviations --- p.ix / List of Compounds --- p.xi / Chapter Chapter One - --- Introduction / Chapter 1.1 --- General Background of Amido Ligands --- p.1 / Chapter 1.2 --- General Background of Guanidinates --- p.2 / Chapter 1.3 --- Coordination modes of Guanidinate Ligands --- p.5 / Chapter 1.4 --- A Brief Review on the Coordination Chemistry of Guanidinate Complexes --- p.7 / Chapter 1.4.1 --- Main Group Metal Guanidinate Complexes --- p.7 / Chapter 1.4.2 --- Transition Metal Guanidinate Complexes --- p.12 / Chapter 1.4.3 --- Rare Earth Metal Guanidinate Complexes --- p.13 / Chapter 1.5 --- Preparations of Metal Guanidinate Complexes --- p.15 / Chapter 1.6 --- Applications of Guanidinate Complexes --- p.16 / Chapter 1.7 --- Objectives of This Work --- p.18 / Chapter 1.8 --- References for Chapter One --- p.19 / Chapter Chapter Two - --- Synthesis and Structural Characterization of Bis(guanidinate) Complexes / Chapter 2.1 --- Introduction to Guanidinate Complexes --- p.25 / Chapter 2.1.1 --- Guanidinate Complexes of the Alkali Metals --- p.25 / Chapter 2.1.2 --- Bis(guanidinate) Complexes of Divalent First-Row Late Transition Metals --- p.27 / Chapter 2.1.3 --- Bis(guanidinate) Complexes of Group 12 Metals --- p.28 / Chapter 2.2 --- Objectives of Our Study --- p.29 / Chapter 2.3 --- Results and Discussion --- p.30 / Chapter 2.3.1 --- Synthesis and Structures of Lithium Guanidinates --- p.30 / Chapter 2.3.1.1.1 --- Synthesis of (L1 = [(C6H3Me2-2J6)NC{N(H)Cy}NCy] (1); L2=[(C6H3Me2-2)6)NC{N(H)Pr/}NPrl (2) and L3 =[(C6H3Me2_2，6)NC{N(SiMe3)Cy}NCy] (5)) --- p.30 / Chapter 2.3.1.1.2 --- Physical Characterization of Compounds 1，2 and 5 --- p.31 / Chapter 2.3.1.1.3 --- Molecular Structures of Compounds 1，2 and 5 --- p.32 / Chapter 2.3.1.2.1 --- Synthesis of Solvated Lithium Guanidinate [Li(L1)(THF)]2(6) --- p.37 / Chapter 2.3.1.2.2 --- Physical Characterization of Compound 6 --- p.37 / Chapter 2.3.1.2.3 --- Molecular Structure of Compound 6 --- p.38 / Chapter 2.3.2 --- Synthesis and Structures of Manganese(ll) Bis(guanidinate) Complexes --- p.40 / Chapter 2.3.2.1 --- Synthesis of Manganese(ll) Bis(guanidinate) Complexes Supported by Ln (n = 1-3) --- p.40 / Chapter 2.3.2.2 --- Physical Characterization of Compounds 7-9 --- p.41 / Chapter 2.3.2.3 --- Molecular Structures of Compounds 7-9 --- p.42 / Chapter 2.3.3 --- Synthesis and Structures of Iron(ll) Bis(guanidinate) Complexes --- p.51 / Chapter 2.3.3.1 --- Synthesis of Iron(ll) Bis(guanidinate) Complexes Supported by Ln (n = 2，3) --- p.51 / Chapter 2.3.3.2 --- Physical Characterization of Compounds 10 and 11 --- p.52 / Chapter 2.3.3.3 --- Molecular Structures of Compounds 10 and 11 --- p.52 / Chapter 2.3.4 --- Synthesis and Structures of Cobalt(ll) Bis(guanidinate) Complexes --- p.57 / Chapter 2.3.4.1 --- Synthesis of Bis(guanidinate) Cobalt(ll) Complexes Supported by Ln (n = 1-3) --- p.57 / Chapter 2.3.4.2 --- Physical Characterization of Compounds 12-14 --- p.57 / Chapter 2.3.4.3 --- Molecular Structures of Compounds 12-14 --- p.58 / Chapter 2.3.5 --- Synthesis and Structures of Nickel(II) Bis(guanidinate) Complexes --- p.65 / Chapter 2.3.5.1 --- "Synthesis of Nickel(ll) Bis(guanidinate) Complexes Supported by Ln (n = 1, 2)" --- p.65 / Chapter 2.3.5.2 --- Physical Characterization of Compounds 15 and 16 --- p.66 / Chapter 2.3.5.3 --- Molecular Structures of Compounds 15 and 16 --- p.66 / Chapter 2.3.6 --- "Synthesis and Structures of Bis(guanidinate) Complexes of Group 12 Metal (M = Zn, Cd)" --- p.71 / Chapter 2.3.6.1 --- Synthesis of Zn(ll) and Cd(ll) Bis(guanidinate) Complexes Supported by Ln (n = 1-3) --- p.71 / Chapter 2.3.6.2 --- Physical Characterization of Compounds 17-20 --- p.72 / Chapter 2.3.6.3 --- Molecular Structures of Compounds 17-20 --- p.72 / Chapter 2.4 --- Summary for Chapter Two --- p.82 / Chapter 2.5 --- Experimental for Chapter Two --- p.83 / Chapter 2.6 --- References for Chapter Two --- p.92 / Chapter Chapter Three - --- "Synthesis and Structural Characterization of Mono(guanidinate) Complexes of Mn(ll), Fe(ll) and Cu(l)" / Chapter 3.1 --- Introduction --- p.95 / Chapter 3.1.1 --- Introduction of Mono(guanidinate) Complexes of the First-Row Divalent Late Transition Metals --- p.95 / Chapter 3.1.2 --- Alkyl Complexes of the Late Transition Metals --- p.99 / Chapter 3.1.3 --- Introduction of Mono(guanidinate) Complexes of Cu(l) --- p.101 / Chapter 3.2 --- Objectives of Our Study --- p.102 / Chapter 3.3 --- Results and Discussion --- p.103 / Chapter 3.3.1 --- Synthesis and Structures of Mono(guanidinate) Complexes Supported by L3 --- p.103 / Chapter 3.3.1.1 --- Synthesis of Mono(guanidinate) Metal (M = Mn 21， Fe 22) Complexes Supported by L3 --- p.103 / Chapter 3.3.1.2 --- Physical Characterization of Compounds 21 and 22 --- p.103 / Chapter 3.3.1.3 --- Molecular Structures of Compounds 21 and 22 --- p.104 / Chapter 3.3.2 --- "Synthesis and Structures of Monoalkyl Metal (M = Mn, Fe) Complexes Supported by the Guanidinate Ligand L3" --- p.110 / Chapter 3.3.2.1 --- "Synthesis of Monoalkyl Metal (M = Mn, Fe) Complexes Supported by the Guanidinate Ligand L3" --- p.110 / Chapter 3.3.2.2 --- Physical Characterization of Compound 23 --- p.111 / Chapter 3.3.2.3 --- Molecular Structure of Compound 23 --- p.111 / Chapter 3.3.3 --- Synthesis and Structure of a Copper(l) Guanidinate Complex Supported by L2 --- p.115 / Chapter 3.3.3.1 --- Synthesis of a Copper(l) Guanidinate Complex Supported by L2 --- p.115 / Chapter 3.3.3.2 --- Physical Characterization of Compound 24 --- p.115 / Chapter 3.3.3.3 --- Molecular Structure of Compound 24 --- p.116 / Chapter 3.4 --- Summary for Chapter Three --- p.119 / Chapter 3.5 --- Experimental for Chapter Three --- p.119 / Chapter 3.6 --- References for Chapter Three --- p.122 / "Appendix 1 - Physical Measurements, X-Ray Structural Analysis" --- p.125 / Appendix 2 - NMR Spectra of Compounds --- p.127 / Appendix 3 - Selected Crystallographic Data --- p.139
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326985 |
| Date | January 2010 |
| Contributors | Yeung, Lai Fong., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiv, 147 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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