During the production of metal zippers, cemented carbide (CC) tools are used to cut preformed brass wire into small elements. Even though the cemented carbide is much harder than the copper alloy, it gets worn and eventually the tool must be replaced. This wear mechanism, which allows soft copper alloys to gradually wear hard CC, must be better understood in order to extend tool life. The mechanism is believed to be tribochemical, as oxides have been found on the surface of the wear mark. Given that most metals oxidize in the presence of oxygen, it is relevant to examine if oxidation of tungsten carbide and cobalt contribute to the wear. The purpose of this work has been to study the influence of oxygen availability on the slow wear of cemented carbides during copper alloy processing. A simplified sliding test rig, developed in a previous study, was used. A small CC cylinder slid against a large rotating copper or brass cylinder in a “crossed cylinders” configuration. The point of contact was encapsulated by a 3D-printed cover. Some tests were done in an oxygen deficient atmosphere, where the cover was continuously filled with flowing nitrogen gas. One test was performed with compressed air flowing through the cover, and one was performed without flowing gas. The wear marks on the CC cylinders were analyzed using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and optical profilometry. The wear volume of these marks was also calculated. SEM pictures showed that both brass and copper transferred to the cemented carbide. When the test was performed with brass, zinc oxide was found in the wear mark. When it was performed with copper, no oxide was found.
| Identifer | oai:union.ndltd.org:UPSALLA1/oai:DiVA.org:uu-508758 |
| Date | January 2023 |
| Creators | Rosengren, Julia |
| Publisher | Uppsala universitet, Tillämpad materialvetenskap |
| Source Sets | DiVA Archive at Upsalla University |
| Language | Swedish |
| Detected Language | English |
| Type | Student thesis, info:eu-repo/semantics/bachelorThesis, text |
| Format | application/pdf |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | UPTEC K, 1650-8297 ; 23031 |
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