Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:27790 |
Date | January 2012 |
Creators | Bon, Volodymyr, Senkovskyy, Volodymyr, Senkovska, Irena, Kaskel, Stefan |
Publisher | Royal Society of Chemistry |
Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
Language | English |
Detected Language | English |
Type | doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
Source | Chemical communications 2012;48:8407-8409, ISSN: 1359-7345 |
Rights | info:eu-repo/semantics/openAccess |
Relation | 10.1039/c2cc34246d |
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