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Previous issue date: 2016-09-15 / Neste trabalho, foi realizada e s?ntese e caracteriza??o de copol?meros a partir de N-isopropilacrilamida(Nipam) e 6-O-viniladipoil-D-glicose(ADG), utilizando as raz?es molares Nipam:ADG 1:9, 3:7, 1:1, 7:3 e 9:1. Tamb?m foram sintetizados e caracterizados os homopol?meros de Nipam e ADG, com intuito avaliar a influ?ncia da adi??o de ADG na cadeia. Os pol?meros foram submetidos ? caracteriza??o por espectroscopia na regi?o do infravermelho (FTIR), resson?ncia magn?tica nuclear de hidrog?nio (1H RMN), reometria e an?lise elementar (CHNO). Os copol?meros obtidos a partir de 30, 50 e 70 mol% de ADG na alimenta??o apresentaram insolubilidade em ?gua. Esse resultado foi associado ? forma??o de arranjos micelares compactados, com superf?cie predominantemente hidrof?lica e n?cleo predominantemente hidrof?bico. Nesses casos, a porcentagem de ADG incorporada, indicada por 1H RMN e CHNO, foi aproximadamente a mesma, o que justifica a diminui??o no rendimento dessas rea??es. Os espectros de FTIR e 1H RMN dos copol?meros comprovaram a inser??o da Nipam e do ADG em todas as amostras. Os copol?meros obtidos a partir de 10% e 90% mol de ADG na alimenta??o foram sol?veis em ?gua e sua composi??o foi determinada por 1H RMN, respectivamente, Nipam:ADG 9:1 e 3:7. O copol?mero Poli(Nipam-co-ADG) 9:1 promoveu um aumento significativo de viscosidade da ?gua, mesmo em baixas concentra??es, que pode ser atribu?do ao seu car?ter associativo. / In this study was performed synthesis and characterization of copolymers from N-isopropylacrylamide (Nipam) and 6-O-vinyladipoyl-D-glucose) (ADG) using the molar ratios of Nipam:ADG 1:9, 3:7, 1:1, 7:3 and 9:1. The homopolymers were also synthesized and characterized, Pnipam and poly(ADG), aiming to evaluate the influence of the addition of ADG in polymer. The polymers were submitted to characterization using spectroscopy in the infrared (FTIR), nuclear magnetic resonance of hydrogen (1H RMN), rheometry and elemental analysis (CHNO). The copolymers obtained from 30%, 50% and 70% mol of ADG feed had water insolubility. This result was associated with the formation of micellar arrangements compact with predominantly hydrophilic surface and core predominantly hydrophobic. In such cases, the percentage of embedded ADG, indicated by 1H NMR and CHNO, was about the same, which explains the decrease in the yield of these reactions. The FTIR and 1H NMR spectra of the copolymers confirmed the insertion of Nipam and the ADG for all samples. The copolymers obtained from 10% to 90% mol of the feed ADG were soluble in water and its composition was determined by 1 H NMR, respectively, Nipam:ADG 9:1 and 3:7. The poly(Nipam-co-ADG) 9:1 produced a significant increase of viscosity in water, even at low concentrations, which can be attributed to its associative character.
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/22376 |
| Date | 15 September 2016 |
| Creators | Celino, Karoline N?brega |
| Contributors | 65946499734, http://lattes.cnpq.br/7711521318854102, Pereira, M?rcia Rodrigues, 83115951787, http://lattes.cnpq.br/5623374421279476, Paula, Regina Celia Monteiro de, 31621252434, http://lattes.cnpq.br/5685898279302235, Balaban, Ros?ngela de Carvalho |
| Publisher | PROGRAMA DE P?S-GRADUA??O EM QU?MICA, UFRN, Brasil |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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