Two framework oxide materials of the MO��� network type have been
synthesized and structurally characterized by synchrotron and X-ray powder
diffraction and the Rietveld method in the temperature range 25~500 K. The results
show one of them to be a low thermal expansion material.
Theoretical studies of negative thermal expansion (NTE) in framework oxides
were conducted with two methods, geometrical modeling by Rigid Unit Mode
(RUM) method and lattice dynamic calculations by free energy minimization
(FEM) method, the results are compared with each other as well as with
experimental observations.
RUM analysis of all five types of framework oxide structures negates any
simple and direct correlation between presence or absence of RUMs in a structure
and the sign of its thermal expansion. Instead, results suggest that NTE of a
crystalline solid can not be explained by pure geometrical considerations over its
structure alone, and for a better understanding of structure-relationship in negative
thermal expansion structures, specific interatomic interactions present in each one
must be brought in explicitly.
FEM calculation of two negative thermal expansion structures indicates on a
structure by structure basis NTE could be predicted and understood within the
Gruneisen model, which attributes NTE of a structure to special vibration modes in
a structure that softens when the lattice shrinks. The soft NTE modes are, however,
not necessarily RUM or RUM like vibration motions. / Graduation date: 2003
| Identifer | oai:union.ndltd.org:ORGSU/oai:ir.library.oregonstate.edu:1957/31094 |
| Date | 10 July 2002 |
| Creators | Tao, Ju Zhou |
| Contributors | Sleight, Arthur W. |
| Source Sets | Oregon State University |
| Language | en_US |
| Detected Language | English |
| Type | Thesis/Dissertation |
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