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Theory of pure vibrational transitions of ¹⁶O₂ in solid parahydrogen.

Yang, Mei. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references (leaves 73-75). / Abstracts in English and Chinese. / THESIS COMMITTEE --- p.II / ABSTRACT --- p.III / 中文摘要 --- p.V / ACKNOWLEDGENTS --- p.VI / TABLE OF CONTENTS --- p.VII / LIST OF FIGURES --- p.IX / LIST OF TABLES --- p.X / Chapter CHAPTER 1 --- INTRODUCTION --- p.1 / Chapter 1.1 --- Matrix isolation spectroscopy --- p.1 / Chapter 1.2 --- Properties of Molecular Hydrogen: A Review --- p.3 / Chapter 1.3 --- Unique properties of solid hydrogen --- p.8 / Chapter CHAPTER 2 --- THEORETICAL BACKGROUND --- p.12 / Chapter 2.1 --- Multipole moments of molecules --- p.12 / Chapter 2.2 --- POLARIZABILITY --- p.14 / Chapter 2.3 --- Pair intermolecular potential --- p.15 / Chapter 2.4 --- Multipole induced transitions --- p.20 / Chapter CHAPTER 3 --- THEORY OF MATRIX ISOLATED 02 IN SOLID PARAHYDROGEN --- p.24 / Chapter 3.1 --- Structural properties of 1602 --- p.24 / Chapter 3.1.1 --- Group theoretical treatment --- p.24 / Chapter 3.1.2 --- Rovibrational wavefunctions and energies --- p.26 / Chapter 3.2 --- O2 isolated in hcp crystal field of parahydrogen --- p.31 / Chapter 3.2.1 --- Group theory --- p.31 / Chapter 3.2.2 --- Crystal field splitting --- p.37 / Chapter 3.2.3 --- Effect of quadrupolar induction --- p.42 / Chapter 3.2.4 --- Pure vibrational transitions --- p.42 / Chapter 3.2.5 --- Calculation of quadrupole matrix elements --- p.47 / Chapter CHAPTER 4 --- RESULTS AND DISCUSSION --- p.54 / Chapter 4.1 --- Results --- p.55 / Chapter 4.1.1 --- Effect of quadrupolar induction --- p.55 / Chapter 4.1.2 --- Crystal field splitting of rovibrational levels of O2 in p-H2 matrix --- p.57 / Chapter 4.1.3 --- Predicted pure vibrational spectrum --- p.64 / Chapter 4.2 --- Discussion and Conclusion --- p.67 / REFERENCE --- p.73

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_327203
Date January 2010
ContributorsYang, Mei., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, x, 75 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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