Die Dissertation befasst sich mit der Darstellung von Iminoboranen sowie deren Verwendung bei der Rhodium-vermittelten Synthese von Azaborininen. / The first examples of adducts of cyclic alkyl(amino) carbenes (cAACs) and N-heterocyclic carbenes (NHCs) with iminoboranes have been synthesized and fully characterized. Furthermore new synthetic route to functionalized 1,2 and 1,4-azaborinines has been developed utilizing a [2+2]/[2+4] cycloaddition reaction of di-tert-butyliminoborane and the unsymmetric (tert-butylimino)mesityborane with a series of alkynes in presence of the rhodium complex [{RhCl(PiPr3)2}]2.
| Identifer | oai:union.ndltd.org:uni-wuerzburg.de/oai:opus.bibliothek.uni-wuerzburg.de:13695 |
| Date | January 2016 |
| Creators | Schäfer, Marius |
| Source Sets | University of Würzburg |
| Language | deu |
| Detected Language | English |
| Type | doctoralthesis, doc-type:doctoralThesis |
| Format | application/pdf |
| Rights | https://opus.bibliothek.uni-wuerzburg.de/doku/lic_mit_pod.php, info:eu-repo/semantics/openAccess |
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