The objective of this report was to implement battery cycling and an intermittent current interruption (ICI) method for determining battery resistance into a simple lithium-ion battery model in the finite element methods (FEM) program COMSOL Multiphysics, andevaluate how accurately the model reflects the behaviour of voltage and internal resistance with respect to experimental results. The ICI technique consists of repeating the steps of first having a longer charging period and then having a short current interruption, where the internal resistance is calculated from the voltage drop that occurs when the current is turned off. The model was evaluated against measurements, made with the same technique (ICI), on assembled NMC-graphite batteries. Codes written in the statistical programming language “R” were used to process the data from both COMSOL and the experiments. Both the batteries and the model were constructed with a reference electrode, to enable measurement of each electrode by itself. The results as documented in this report show that it is possible to simulate the measurement technique in COMSOL, but that both the resistance and voltage profiles differed quite a lot from the behaviour of the tested batteries. The resistance of the positive electrode did however give good results and it was possible to improve the model by changing some parameters. The magnitude of the resistance, which was already quite close, could be improved by changing the porosity and particle size, and the voltage profiles were improved when using voltage-data achieved from the real measurements.
| Identifer | oai:union.ndltd.org:UPSALLA1/oai:DiVA.org:uu-325298 |
| Date | January 2017 |
| Creators | Lindqvist, Daniel |
| Publisher | Uppsala universitet, Strukturkemi |
| Source Sets | DiVA Archive at Upsalla University |
| Language | English |
| Detected Language | English |
| Type | Student thesis, info:eu-repo/semantics/bachelorThesis, text |
| Format | application/pdf |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | UPTEC ES, 1650-8300 ; 17 030 |
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