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Ionic Conductivity and Electrochemical s Reactions of Rigid-Rod Solid Polyelectrolytes

ABSTRACT
sPBI is a heterocyclic aromatic polymer assuming a para- catenated backbone yielding a rod-like configuration. Because of its rigidity, this rod-like molecule displays superior mechanical tenacity, thermo-oxidative stability, and solvent resistance. It is also the precursor of rigid-rod solid polyelectrolyte exhibiting high solubility and superior ionic conductivity.
Isotropic solution were prepared by dissolving sPBI in distilled methanesulfonic acid containing 0.0, 0.989, 4.76, 9.09, 15.0, 20.0, 23.1 wt. % lithium ion of dopants of LiCF3SO3 or LiN(CF3SO2)2. The room-temperature DC conductivity of sPBI cast film doped with 15.0 wt. % LiN(CF3SO2)2 parallel (

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0714103-013011
Date14 July 2003
CreatorsLin, Chia-Hung
ContributorsJin-Long Hong, Bae-Heng Tseng, Shih-Jung Bai
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0714103-013011
Rightsnot_available, Copyright information available at source archive

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