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Homogenní a heterogenní titaničité komplexy pro selektivní trimerizaci ethylenu na 1-hexen / Homogeneous and heterogeneous titanium complexes and their use for selective ethylene trimerization to 1-hexene

This diploma thesis is focused on the design and synthesis of new half-sandwich titanium complexes for anchoring to selected supports (SiO2, SBA-15) and the study of their catalytic activity and selectivity in ethylene trimerization to 1-hexene. The synthetic strategy of half-sandwich titanium complexes with a suitable leaving group for direct anchoring through Ti−O bond was carried out (Cl, Oi-Pr). In addition, the titanium complexes with pendant alkenyl group were prepared and utilised for anchoring to a SiMe2H modified support by Pt-catalysed hydrosilylation reaction. Prepared compounds were characterised by standard spectroscopic methods (IR, NMR, MS). The heterogeneous systems were characterised by MAS NMR and IR spectroscopy, powder XRD, ICP-OES, TGA and the textural parameters were determined from nitrogen adsorption/desorption isotherms. For all prepared materials was studied the catalytic activity for ethylene trimerization and the selectivity to 1-hexene.

Identiferoai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:350911
Date January 2015
CreatorsHodík, Tomáš
ContributorsPinkas, Jiří, Merna, Jan
Source SetsCzech ETDs
LanguageEnglish
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/masterThesis
Rightsinfo:eu-repo/semantics/restrictedAccess

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