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Využití různých frakcionačních technik pro studium struktury ICP / Application of different fractionation techniques for structure determination of ICP

Impact E/P copolymer (ICP) is produced using gas-phase polymerization catalysed by Ziegler-Natta catalysts. This material with its excellent mechanical properties is used in many industries, for example in automotive industry to produce bumpers or instrument panels. Its properties depend on chemical structure which was analysed using DSC, 13C NMR and GPC. It was used 6 different samples of ICP for studies, the chosen samples have different ratio between ethylene and propylene in their copolymer phase. The samples were fractionated using preparative TREF and solvent extraction to obtain fractions, which composition depends on elution temperature. Obtained fractions and original samples were subsequently analysed using above-mentioned methods.

Identiferoai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:217144
Date January 2015
CreatorsDostálová, Dagmar
ContributorsKratochvíla,, Jan, Buráň,, Zdeněk
PublisherVysoké učení technické v Brně. Fakulta chemická
Source SetsCzech ETDs
LanguageCzech
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/masterThesis
Rightsinfo:eu-repo/semantics/restrictedAccess

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