New one- and two-dimensional NMR techniques were used to elucidate the solution structures of these complex mixtures. The system, lithium tert-butoxide/tert-butyllithium, was studied as a model system with O/Li ratios varying from 0/1 to 1/1. It was found that at low O/Li ratios, a single mixed tetrameric aggregate was formed. At higher O/Li ratios, mixed hexameric species were formed. Two other systems, lithium isopropoxide/iso-propyllithium and lithium n-propoxide/n-propyllithium were also studied at low O/Li ratios.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc279031 |
| Date | 12 1900 |
| Creators | DeLong, George T. (George Thomas) |
| Contributors | Thomas, Ruthanne D., Theriot, L. J., Schwartz, Martin, Jones, Paul R., Kunz, Daniel A. |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | xiii, 322 leaves: ill., Text |
| Rights | Public, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., DeLong, George T. (George Thomas) |
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