by Feng Xue. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 76-84). / ACKNOWLEDGMENTS --- p.I / ABSTRACT --- p.II / TABLE OF CONTENTS --- p.III / LIST OF TABLES --- p.V / LIST OF FIGURES --- p.VI / Chapter CHAPTER 1: --- INTRODUCTION --- p.1 / Chapter 1. --- supramolecular chemistry --- p.1 / Chapter 2. --- Infinite multi-dimensional architecture --- p.10 / Chapter 3. --- Chemistry of pseudohalides --- p.15 / Chapter 4. --- Chemistry of hexamethylenetetramine --- p.20 / Chapter 5. --- Objectives of the present research --- p.24 / Chapter CHAPTER 2: --- EXPERIMENTAL --- p.25 / Chapter 1. --- Preparation --- p.25 / Chapter 1.1 --- Materials --- p.25 / Chapter 1.2 --- Preparation of the compounds --- p.25 / Chapter 2. --- X-ray crystallography --- p.26 / Chapter CHAPTER 3: --- DESCRIPTION OF CRYSTAL STRUCTURES --- p.28 / Chapter 1. --- isostructural compounds K2[FEII(CN)6] ´Ø 2[(CH2)6n4H] ´Ø 4H2 O(1) and K2[FEIII(CN)6] ´Ø [(CH2)6N4H] ´Ø [(CH2)6N4] ´Ø 4H2O (2) --- p.28 / Chapter 2. --- Crystal structure of NA2[FEIII(CN)6] ´Ø [(CH2)6N4H] ´Ø [(CH2)6N4] ´Ø 5H2O (3) --- p.33 / Chapter 3. --- Crystal structure of K3[FEIII(CN)6] ´Ø 2[(CH2)6N4] ´Ø 4H2O (4) --- p.37 / Chapter 4. --- Crystal Structure of ferricyanic acid-HMT adduct H3[FEIII(CN)6] ´Ø 2[(CH2)6N4] ´Ø 2H2O (5) --- p.43 / Chapter 5. --- "Crystal structure of cadmium chloride-HMT adduct, Cd2[C6H12N4H2]Cl6´Ø 3H2O (6)" --- p.48 / Chapter 6. --- "Crystal structure of cadmium bromide-HMT adduct, CdBr2 ´Ø 2[(CH2)6N4] ´Ø 2H2O (7)" --- p.53 / Chapter 7. --- "Crystal structure of cadmium iodide-HMT adduct, 3CdI2 ´Ø 2[(CH2)6N4] ´Ø 4H2O (8)" --- p.57 / Chapter 8. --- Crystal structure of cadmium thiocyanate-HMT adduct Cd(SCN)2 ´Ø 1(CH2)6N4] ´Ø MeOH (9) --- p.61 / Chapter 9. --- Crystal structure of cobalt cyanate-HMT adduct Co(NCO)2 ´Ø [(CH2)6N4] ´Ø 2H2O (10) --- p.67 / Chapter CHAPTER 4: --- SUMMARY AND DISCUSSIONS --- p.72 / REFERENCES --- p.76 / TABLE A1 Crystallographic data for compounds 1 ~5 --- p.85 / TABLE A2 Crystallographic data for compounds 6~10 --- p.86 / APPENDIX 1 Atomic Coordinates (Ax 104) and Equivalent Isotropic Thermal Parameters (A 2x103) --- p.87 / APPENDIX 2 Anisotropic thermal parameters (A2x 103) --- p.92 / APPENDIX 3 H-atom coordinates (x 104) and isotropic thermal parameters (A2x 103) --- p.96
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321544 |
| Date | January 1996 |
| Contributors | Xue, Feng., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Publisher | Chinese University of Hong Kong |
| Source Sets | The Chinese University of Hong Kong |
| Language | English |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, ix, 99 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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