Ligands prepared from various combinations of aldehydes and ketones with the appropriate aminealcohol were complexed with cupric acetate monohydrate. The complexes with O,NO or N,N,O donor atoms were synthesized to study the influences of the ligand on molecular structure, spin-spin interaction, and on the value of the exchange integral. The magnetic data indicated that of the eight Cu(II) complexes discussed, two behaved differently from known analogous compounds. Cu (benzoylacetone :ethanolamine) was compared to Cu(acac:ethanolamine), and Cu(pyrr:oaminophenol) was compared to Cu(acac:o-aminophenol). Each pair of complexes was postulated to have the same molecular structure. The synthesis and characterization of Mn(pyrr:oaminophenol) 2H2 is also discussed. The following physical data were collected and discussed: elemental analysis, melting point, molecular weight, infrared spectra, electronic spectra, and magnetic susceptibility.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc663278 |
| Date | 05 1900 |
| Creators | Hines, Mary Katherine |
| Contributors | Theriot, L. J., Desiderato, Robert |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vii, 148 leaves: ill., Text |
| Rights | Public, Hines, Mary Katherine, Copyright, Copyright is held by the author, unless otherwise noted. All rights |
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