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Studies of geometrical isomers by photo-ionization mass spectrometry

A series of isomeric tricyclic [3.2.1.0²̕⁴] oct-8—[symbols omitted] derivatives have been studied by photoionization mass spectrometry and the low resolution mass spectra of the compounds obtained. The observed differences in the relative intensities in the spectra of the isomers are explained on the basis of the geometry of the tricyclic system.
The major fragments of the low resolution spectra were 'mass measured' to determine their elemental composition and, from the information obtained, possible fragmentation pathways are postulated.
In addition, the ionization potential of all isomers was determined by electron impact. / Science, Faculty of / Chemistry, Department of / Graduate

Identiferoai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/35269
Date January 1968
CreatorsStewart, William Brien
PublisherUniversity of British Columbia
Source SetsUniversity of British Columbia
LanguageEnglish
Detected LanguageEnglish
TypeText, Thesis/Dissertation
RightsFor non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.

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