by Tung Suet Lam. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgments --- p.iv / Abstract --- p.v / Abstract (Chinese version) --- p.vii / Abbreviations --- p.ix / List of Compounds --- p.xi / Chapter Chapter1. --- synthesis and structures of iron(ii) and cobalt(ii) complexes derived from pyridine-functionalized amido ligands / Chapter 1.1 --- INTRODUCTION --- p.1 / Chapter 1.1.1 --- General Background --- p.1 / Chapter 1.1.2 --- A Brief Review on Amides of the Late Transition Metals --- p.3 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.5 / Chapter 1.3 --- RESULTS AND DISCUSSION --- p.7 / Chapter 1.3.1 --- Alkali Metal Derivatives of N-Silylated 2-Aminopyridines --- p.7 / Chapter 1.3.1.a. --- "Synthesis of Aminopyridines [HN(SiMe3)》(2-C5H3N-6-R)] (R=H (1a), Me (1b)) and Their Lithium Derivatives" --- p.7 / Chapter 1.3.1.b. --- Synthesis of the Potassium Derivative [{K(L1)(tmeda)}2 ] (4) --- p.8 / Chapter 1.3.1.c. --- "Physical Characterization of Compounds 2a, 3 and" --- p.4 9 / Chapter 1.3.1.d. --- Molecular Structures of Compounds 3 and4 --- p.10 / Chapter 1.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amides" --- p.16 / Chapter 1.3.2.a. --- Synthesis of Mononuclear Iron(II) and Cobalt(II) Diamides --- p.16 / Chapter 1.3.2.b. --- Physical Characterization of Compounds 5-8 --- p.16 / Chapter 1.3.2.C. --- Molecular Structures of Compounds 5-8 --- p.17 / Chapter 1.4 --- EXPERIMENTAL FOR CHAPTER1 --- p.28 / Chapter 1.5 --- REFERENCES FOR CHAPTER1 --- p.31 / Chapter Chapter2. --- reaction of iron(II) and cobalt(II) amides with phenolic compounds / Chapter 2.1 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) BIS(ARYLOXIDE)" --- p.36 / Chapter 2.1.a. --- "Reaction of Compounds 7 and 8 with 2,2 -ethylidenebis(4,6-di-tert-butyl phenol)" --- p.36 / Chapter 2.1.b. --- "Molecular Structures, Magnetic Moments, and Reactivities of Compounds 9and10" --- p.36 / Chapter 2.2 --- A GENERAL REVIEW ON CATECHOL DIOXYGENASES --- p.44 / Chapter 2.3 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) CATECHOLATES" --- p.46 / Chapter 2.3.a. --- Synthesis of Binuclear Iron(II) and Cobalt(II) Catecholates --- p.46 / Chapter 2.3.b. --- Molecular Structures of Compounds 11 and12 --- p.48 / Chapter 2.3.c. --- Reactions of Compounds 11 and 12 with Dioxygen --- p.54 / Chapter 2.3.d. --- Identification of Oxidative Cleavage Products --- p.54 / Chapter 2.4 --- EXPERIMENTAL FOR CHAPTER2 --- p.56 / Chapter 2.5 --- REFERENCES FOR CHAPTER2 --- p.59 / Chapter Chapter3. --- synthesis of late transition metal amidinates / Chapter 3.1 --- INTRODUCTION --- p.62 / Chapter 3.1.1 --- General background --- p.62 / Chapter 3.1.1.a --- Metal´ؤAmidine Bonding Modes --- p.63 / Chapter 3.1.1.b. --- Preparation of Metal Amidinates Complexes --- p.64 / Chapter 3.1.2 --- "N-Silylated Benzamidinates of Li, Na and K 一 The Starting Materials" --- p.65 / Chapter 3.1.3 --- A General Review on The Chemistry of Low-Valent Late Transition- Metal Amidinates --- p.67 / Chapter 3.2 --- OBJECTIVES OF THIS WORK --- p.72 / Chapter 3.3 --- RESULTS AND DISCUSSION --- p.73 / Chapter 3.3.1 --- Synthesis and Structures of Lithium Benzamidinates --- p.73 / Chapter 3.3.1.a. --- "Synthesis of [Li(L3)(tmeda)] (L3 = [PhC(NSiMe3){N(2,6´ؤ Me2C6H3}]) and [Li(L4)(tmeda)] (L4 = [PyC(NSiMe3){N(2,6- Me2C6H3)}]) as Ligand´ؤTransfer Reagents" --- p.73 / Chapter 3.3.1.b. --- Physical Characterization of Compounds 15 and16 --- p.74 / Chapter 3.3.1.c. --- Molecular Structures of Compounds 15 and16 --- p.75 / Chapter 3.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amidinates" --- p.81 / Chapter 3.3.2.a. --- Synthesis of Mononuclear Iron(II) Benzamidinates --- p.81 / Chapter 3.3.2.b. --- Synthesis of a Binuclear Cobalt(II) Benzamidinate --- p.82 / Chapter 3.3.2.c. --- Physical Characterization of Compounds 17-19 --- p.83 / Chapter 3.3.2.d. --- Molecular Structures of Compounds 17-19 --- p.84 / Chapter 3.3.2.e. --- Reaction of Compound 18 with Dioxygen --- p.94 / Chapter 3.3.2.f. --- Molecular Structure of Compound20 --- p.95 / Chapter 3.3.3 --- Synthesis and Structures of Nickel(II) and Copper(I) Benzamidinates --- p.98 / Chapter 3.3.3.a --- Synthesis of a Nickel(II) Benzamidinate --- p.98 / Chapter 3.3.3.b. --- Synthesis of a Binuclear Copper(I) Benzamidinate --- p.99 / Chapter 3.3.3.c. --- Physical Characterization of Compounds 21 and22 --- p.101 / Chapter 3.3.3.d. --- Molecular Structures of Compounds 21 and22 --- p.102 / Chapter 3.3.4 --- Synthesis and Structures of Mononuclear Zinc(II) and Cadmium(II) Amidinates --- p.107 / Chapter 3.3.4.a --- Synthesis of Mononuclear Zinc(II) and Cadmium(II) Benzamidinates --- p.107 / Chapter 3.3.4.b. --- Physical Characterization of Compounds 23 and24 --- p.107 / Chapter 3.3.4.C. --- Molecular Structures of Compounds 23 and24 --- p.108 / Chapter 3.4 --- EXPERIMENTAL FOR CHAPTER3 --- p.113 / Chapter 3.5 --- REFERENCES FOR CHAPTER3 --- p.119 / appendix1 --- p.127 / appendix2 --- p.129
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323874 |
| Date | January 2002 |
| Contributors | Lam, Tung Suet., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xv, 138 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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