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Synthesis and structural characterization of some metal complexes of phosphorus-containing ligands. / Heterobimetallic complexes of PPh2, trans-(CO)3Fe(Ph2Ppy)2 and trans-(CO)3Fe(Ph2Ppym)2 / Metal complexes of tertiary phosphine betaines

pt I. Heterobimetallic complexes of PPh2, trans-(CO)3Fe(Ph2Ppy)2 and trans-(CO)3Fe(Ph2Ppym)2 -- pt II. Metal complexes of tertiary phosphine betaines. / by Song-Lin Li. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 77-83, 167-173). / Acknowledgments / Abstract --- p.i-ii / Table of Contents --- p.iii-iv / Structural Formulas of Ligands --- p.v / Index of Compounds --- p.vi-vii / List of Tables --- p.viii-ix / List of Figures --- p.x-xii / Chapter Part I. --- " HeterobimetaUic Complexes of PPh2-, trans- (CO)3Fe(Pli2Ppy)2 and trans-(CO)3Fe(Ph2Ppym)2" --- p.1 - 83 / Chapter 1. --- Introduction --- p.1-11 / Chapter 2. --- Results and Discussion / Chapter 1. --- "Synthetic and Structural Characterization of the Phosphido-Bridgcd Heterobimetallic Transition Metal Complex, (OC)3Fe(μ-PPh2)2Mo(CO)4" --- p.12-18 / Chapter 2. --- ############################################################################################################################################################################################################################################################### --- p.19-36 / Chapter 3. --- Coordination Chemistry of a New Neutral Organomctallic Tridcntate Ligand trans-(CO)3Fe(Ph2Ppym)2 (Ph2Ppym = 2-(di --- p.37-76 / Chapter 1. --- Synthesis and Crystal Structure of trans-(CO)3Fe(Ph2Ppym)2 --- p.38-42 / Chapter 2. --- "Mono-, Di- and Tridcntate Coordination Modes of trans-(CO)3Fe(Ph2Ppym)2 Towards Mercury(II) Halide/Pscudohalide" --- p.42-52 / Chapter 3. --- "Synthesis and Crystal Structures of Complexes Containing an Fe→Cd Donor-Acceptor Bond Formed by Reaction of trans-(CO)3Fe(Ph2Ppym)2 with CdX2 (X = C1, Br, I,SCN, C1O4)" --- p.53-65 / Chapter 4. --- "Miscellaneous: Interaction of trans-(CO)3Fe (Ph2Ppym)2 with Hg2(ClO4)2.xH2O,[(cod)RhCl]2, (cod)PdCl2, PdCl2 and Nd(SCN)3 .xH2O" --- p.66-76 / References --- p.77-83 / Chapter Part II. --- Metal Complexes of Tertiary Phosphine Betaines --- p.84-173 / Chapter 3. --- Introduction --- p.84-96 / Chapter 4. --- Results and Discussion / Chapter 1. --- Betaine Derivatives --- p.97-109 / Chapter 2. --- Cadmium(II) Complexes with Tertiary Phosphine Bctaincs --- p.110-145 / Chapter 1. --- """Paddle wheel-like"" cadmium(II) complexes" --- p.111-116 / Chapter 2. --- "Discrete Mono-, Bi-, Tri- and Tctra-nuclcar Complexes of Cadmium(II) with Ph3P+(CH2)2CO2-" --- p.116-129 / Chapter 3. --- A Layer-Type Complex of Cadmium(II) Chloride/Pcrchlorate with Triphenylphosphoniopropionate (Ph3P+(CH2)2C02 -) --- p.130-133 / Chapter 4. --- A Layer-Type Complex of Cadmium(II) Chloride/Pcrchlorate with Triphenylphosphoniopropionate (Ph3P+(CH2)2C02-) --- p.134-139 / Chapter 5. --- Mixed-ligand Cadmium(II) Complexes of Ph3P(CH2)2CO2- and Me2N(CH2)2NMe2 (tmen) --- p.139-144 / Chapter 3. --- Zinc(II) and Mercury(II) Complexes --- p.146-155 / Chapter 1. --- Synthesis and Structural Characterization of Mono- and Dinuclcar Zinc(II) Complexes of Triphenylphosphoniopropionate --- p.146-151 / Chapter 2. --- Interaction of Mercury(II) Halidcs with Tertiary Phosphine Bctaines --- p.151-155 / Chapter 4. --- "Cobalt(II), Copper(II) and Silver(I) Complexes" --- p.156-166 / References --- p.167-173 / Chapter 5. --- Conclusion --- p.174-178 / Chapter 6. --- Experimental --- p.179-203 / Appendix A Table of Atomic Coordinates and Thermal Parameters --- p.204-226 / Publications based on results reported in this thesis --- p.227-228

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321655
Date January 1996
ContributorsLi, Song-Lin., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xii, 227 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)
RelationHeterobimetallic complexes of PPh2, trans-(CO)3Fe(Ph2Ppy)2 and trans-(CO)3Fe(Ph2Ppym)2, Metal complexes of tertiary phosphine betaines

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