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The Synthesis of Magnesium Metal-Organic Framework Film for Ion Transport in Magnesium Battery

Thesis advisor: Dunwei Wang / Metal organic frameworks (MOFs) are a class of compounds that show promising potential for a variety of applications due to their uniformity, highly porous structure, lack of dead volume, and fine-tunability. One of these significant applications is in selective ion transport, which makes MOF films a uniquely good separatory material for dual-electrolyte setups, such as those being investigated with Mg-Br batteries. This research has important environmental and industrial ramifications, considering the various drawbacks associated with commercially available batteries such as the lithium-ion battery. The MOF investigated was Mg-MOF-74, which showed promising selective Mg2+ transport abilities. Both Mg-MOF-74 powder and films were synthesized via a vapor-assisted conversion process to maximize efficiency. To characterize the MOF, XRD and SEM imaging was used. This allowed us to gain a nuanced understanding of the material and its properties for further applications. / Thesis (BA) — Boston College, 2022. / Submitted to: Boston College. College of Arts and Sciences. / Discipline: Departmental Honors. / Discipline: Chemistry.

Identiferoai:union.ndltd.org:BOSTON/oai:dlib.bc.edu:bc-ir_109512
Date January 2022
CreatorsProstko, Gabriela
PublisherBoston College
Source SetsBoston College
LanguageEnglish
Detected LanguageEnglish
TypeText, thesis
Formatelectronic, application/pdf
RightsCopyright is held by the author, with all rights reserved, unless otherwise noted.

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