Knowledge of radical initiated grafting was summarized in theoretical part. It also contains a part about adamantane, its derivatives and a study of their use in polymer chemistry. In experimental part radical grafted polypropylene was prepared in batch mixer Brabender at 185 and 195 °C, 40 RPM and reaction time 5 min. Initiator 2,5-dimethyl-2,5-bis(tert-buthylperoxy)hexane (Trigonox 101) in concentrations between 0,2 – 4 wt % was used. 1-vinyladamantane was chosen as a monomer and its concetration ranged from 0,75 to 2,24 wt %. Mechanical properties of prepared samples were tested. Sample with content of initiator 0,2 wt % and monomer 1,4 wt % showed increase in notch toughness by 56,3 %, strength by 8,7 %, ductility by 11,5 % and decrease in MFR (230 °C; 2,16 kg) by 29,7 %. Values of torque indicated grafting reactions which couldn’t be proven by use of FTIR method so more suitable methods have been proposed.
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:438898 |
| Date | January 2018 |
| Creators | Svítil, Jan |
| Contributors | Kučera, Jaroslav, Petrůj, Jaroslav |
| Publisher | Vysoké učení technické v Brně. Fakulta chemická |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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