In contrast to traditional conjugated polymer, the non-conjugated polycyanate
network represents an interesting example to work with. Close packings among the
phenylene and s-triazine rings in polycyanate may introduce £k-£k interaction and
thereby, induce light emission. There is an important relationship between molecular
packing and photo-luminescence properties. To clarify it, we also add aromatic
fluorophore to hopefully alter the packing situation and from the response, further
evaluation can be made.
Detailed molecular packing in the network polycyanate can be evaluated by the
molecular simulation technique. The simulation results for the pure polycyanate show
that the most-likely inter-ring distance is 3 ~ 5
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0720105-113508 |
| Date | 20 July 2005 |
| Creators | Chiu, Chen-Wei |
| Contributors | Cheng-Lung Chen, Jui-Hung Hsu, Ming Chen, Jin-Long Hong |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0720105-113508 |
| Rights | restricted, Copyright information available at source archive |
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