The products of the decomposition of selected types of peroxo compounds in the presence of redox agents (Pb and Co compounds) were investigated by EPR method. Besides some commercial peroxides the study was performed with peroxo compounds of Luperoxide group (Luperox 101, Luperox 256, Luperox 531). For the detection of the decomposition products the technique of spin-trapping using nitrosobenzene was applied. EPR spectra of radical adducts formed by the reaction of the reactive oxygenous radicals with nitrosobenzen having the character of stable nitroxyl radicals were analyzed. Their EPR parameters were obtained by simulation method. Besides the addition to nitrosobenzene the generated oxygen centered radicals were proved also on the basis of their reaction with model compounds (Santonox R; 2,6–ditercbutyl–4–methylphenol; diphenylamine).
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:216570 |
| Date | January 2010 |
| Creators | Krkošková, Petra |
| Contributors | Kučerík, Jiří, Omelka, Ladislav |
| Publisher | Vysoké učení technické v Brně. Fakulta chemická |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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