Kwong Wai-chuen. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 98-102). / Abstracts in English and Chinese. / Acknowledgement --- p.I / Abstract (in English) --- p.II / Abstract (in Chinese) --- p.III / Abbreviation --- p.V / List of Compounds --- p.VI / Contents --- p.VII / Chapter Chapter 1. --- Introduction / Chapter 1.1 --- Metallacarboranes of the C2B4 Systems --- p.1 / Chapter 1.1.1 --- Group 1 Metallacarboranes of the C2B4 Systems --- p.3 / Chapter 1.1.2 --- Group 4 Metallacarboranes of the C2B4 Systems --- p.6 / Chapter 1.2 --- Group 4 Metallacarboranes of the C2B9 Systems --- p.17 / Chapter 1.3 --- Group 4 Metallacarboranes of the C2B10 Systems --- p.35 / Chapter 1.4 --- Applications of Group 4 Metallacarboranes --- p.44 / Chapter 1.5 --- Research Objectives --- p.47 / Chapter Chapter 2. --- Synthesis and Structural Characterization of Group4 Metallacarboranes of the C2B9 Systems / Chapter 2.1 --- Synthesis and Structural Characterization of {{466}4:η2-[(C6H5CH2)2C2B9H9]2ZrCl(THF)} {Na(THF)3} --- p.48 / Chapter 2.2 --- Synthesis and Structural Characterization of [η4:η2- {(C6H5CH2)2C2B9H9} 2ZrCl(THF)] [Li(THF)4] --- p.54 / Chapter 2.3 --- Synthesis and Structural Characterization of ZrCl[N(SiMe3)2]3 --- p.57 / Chapter 2.4 --- "Synthesis and Structural Characterization of η2-(C6H5CH2)2C2B9H9]M(NEt2)2(NHEt2HCH2Cl2) (M = Ti, Zr)" --- p.62 / Chapter 2.5 --- "Synthesis and Structural Characterization of [μ-{ o-C6H4(CH2)2 }C2B9H9]2M(THF)2 (M = Zr, Hf)" --- p.68 / Chapter 2.6 --- Conclusion --- p.71 / Chapter Chapter 3. --- Synthesis and Structural Characterization of Group4 Metallacarboranes of the C2B10 Systems / Chapter 3.1 --- "Synthesis and Structural Characterization of {{471}-l,，2-(o-C6H4(CH2)2)- 1,2-C2B 10H10]2Zr} {Na(THF)3}2 and {[μ-l，2-(o-C6H4(CH2)2)-l,2- C2B10H10]2ZrCl2} {Na(THF)3}2(THF)" --- p.72 / Chapter 3.2 --- Conclusion --- p.78 / Chapter Chapter4. --- Summary --- p.79 / Chapter Chapter5. --- Experimental Section --- p.81 / References --- p.98 / Appendix / Chapter I. --- Crystal Data and Summary of Data Collection and Refinement --- p.103 / Chapter II. --- Atomic Coordinates and Thermal Parameters --- p.109 / Chapter III. --- Bond Distances and Angles --- p.117
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323911 |
| Date | January 2002 |
| Contributors | Kwong, Wai-chuen., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, viii, 134 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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