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Synthesis of covalently-linked porphyrin-quinones and their metal complexes.

by Chi-Shing Chan. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. / Includes bibliographical references (leaves 62-65). / Acknowledgements --- p.i / Contents --- p.ii / Abbreviations --- p.iii / Abstract --- p.1 / Introduction --- p.2-8 / Synthetic Strategy --- p.9-12 / Results and Discussion / Chapter A. --- Synthesis of the aryl triflate substituted and aryl bromide substituted porphyrins --- p.13-15 / Chapter B. --- Synthesis of the (alkynyl)phenyl substituted porphyrins --- p.16-19 / Chapter C --- Benzannulation of Fischer carbene complexes with (alkynyl)phenyl substituted porphyrins --- p.20-23 / Chapter D. --- "Palladium-catalysed cross coupling reaction of 2,5-dimethoxyphenyl boronic acid with aryl triflate or aryl bromide substituted porphyrins" --- p.24-28 / Chapter E. --- Synthesis of the meso-tetrakis(benzoquinonyl) porphyrin --- p.29 / Chapter F. --- Metalation of the quinone-linked porphyrins --- p.30 / Chapter G. --- Preliminary study on the electrocatalytic activity of the quinone-linked metalloporphyrin complexes of cobalt and palladium for the electrochemical reduction of carbon dioxide --- p.31 / Conclusion --- p.32 / Experimental --- p.33-61 / References --- p.62-65 / List of spectra / Porphyrin aryl triflate4 --- p.66 / (Alkynyl)phenyl porphyrin 9 d --- p.67 / Tetra(quinonyl)phenyl porphyrin 12a --- p.68 / (Naphthoquinonyl)phenyl porphyrin 13b --- p.69 / "2,5 -dimethoxyphenyl boronic acid 16" --- p.70 / (Benzoquinonyl)phenyl porphyrin19 --- p.71 / Tetra(quinonyl)phenyl porphyrin 23 --- p.72

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_319168
Date January 1993
ContributorsChan, Chi-shing., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, iii, 72 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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