Ho, Ming Gong. / "October 2009." / Thesis (M.Phil.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references (leaves 72-75). / Abstracts in English and Chinese. / Table of Contents --- p.V / Acknowledgements --- p.i / Abstract --- p.ii / 摘要 --- p.iv / List of Compounds Synthesized --- p.X / Abbreviation --- p.xi / Chapter Chapter 1 --- Synthesis and Characterization of (9-Anthryl)(iminophosphorano)methanide Group 14 Metal Complexes / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.1.1 --- A General Review of Phosphoranoimine Ligands --- p.1 / Chapter 1.1.2 --- A General Review of Group 14 Metal Complexes Containing Phosphoranoimine Ligands --- p.8 / Chapter 1.2 --- Objectives --- p.9 / Chapter 1.3 --- Results and Discussion --- p.10 / Chapter 1.3.1.1 --- Synthesis of (9-Anthryl)(iminophosphorano)methanide Germanium(II) Chloride [Ge{CH(Pri2P=NSiMe3)(Anth)}Cl] (44) and (9-Anthryl)(iminophosphorano)methanide Tin(II) Chloride [Sn{CH(Pri2P=NSiMe3)(Anth)}Cl] (45) --- p.10 / Chapter 1.3.1.2 --- Spectroscopic Properties of 44 and 45 --- p.11 / Chapter 1.3.1.3 --- Molecular Structures of [Ge {CH(Pri2P=NSiMe3)(Anth)} Cl] (44) and [Sn{CH(Pri2P=NSiMe3)(Anth)} Cl] (45) --- p.11 / Chapter 1.3.2.1 --- Synthesis of Homoleptic Dialkylstannylene [Sn{CH(Pr/2P=NSiMe3)(Anth)}2] (46) --- p.16 / Chapter 1.3.2.2 --- Spectroscopic Properties of 46 --- p.17 / Chapter 1.3.2.3 --- Molecular Structure of [Sn{CH(Pri2P=NSiMe3)(Anth)}2] (46) --- p.17 / Chapter 1.4 --- Experimental Section --- p.20 / Chapter 1.5 --- References for Chapter 1 --- p.23 / Chapter Chapter 2 --- "Synthesis, Characterization and Catalytic Study of (9-Anthryl)(iminophosphorano)methanide Group 4 Metal Complexes" / Chapter 2.1 --- Introduction --- p.27 / Chapter 2.1.1 --- A General Review of Group 4 Metallocene Catalysts in Olefin Polymerization --- p.27 / Chapter 2.1.2 --- A General Review of Group 4 Metal Complexes --- p.28 / Chapter 2.2 --- Results and Discussion --- p.31 / Chapter 2.2.1.1 --- Synthesis of (9-Anthryl)(iminophosphorano)methanide Zirconium(IV) Chloride [Zr{CH(Pri2P=NSiMe3)(Anth)} 2CI2] (57) and (9-Anthryl)(iminophosphorano)methanide Hafnium(IV) Chloride [Hf{CH(Pri2P=NSiMe3)(Anth)}2Cl2] (58) --- p.31 / Chapter 2.2.1.2 --- Spectroscopic Properties of 57 and 58 --- p.32 / Chapter 2.2.1.3 --- Molecular Structures of [Zr{CH(Pri2P^NsiMe3)(Anth)}2CI2] (57) and [Hf{CH(Pri2P=NsiMe3)(Anth)}2Cl2] (58) --- p.32 / Chapter 2.3 --- Catalytic Study of Compounds 57 and 58 on Ethylene Polymerization --- p.37 / Chapter 2.4 --- Experimental Section --- p.39 / Chapter 2.5 --- Reference for Chapter 2 --- p.41 / Chapter Chapter 3 --- "Synthesis, Characterization and Catalytic Study of (9-Anthryl)(thiophosphinoyl)methanide Metal Complexes" / Chapter 3.1 --- Introduction --- p.45 / Chapter 3.2 --- A General Review of Phosphoranosulfide Ligands --- p.45 / Chapter 3.3 --- Objectives --- p.54 / Chapter 3.4 --- Results and Discussion --- p.55 / Chapter 3.4.1.1 --- Synthesis of (9-Anthryl)(thiophosphinoyl)methane [CH2(Pri2P=S)(Anth)] (92) and Lithium Compound [Li(THF)2{CH(Pr/2P=S)(Anth)}] (93) --- p.55 / Chapter 3.4.1.2 --- Spectroscopic Properties of 92 and 93 --- p.56 / Chapter 3.4.1.3 --- Molecular Structures of [Li(THF)2{CH(Pri2P=S)(Anth)}] (93) --- p.57 / Chapter 3.4.2.1 --- Synthesis of Germylgermylene [Ge(GeCl){CH(Pri2P=S)(Anth)}2C12C6H5CH3] (94) --- p.59 / Chapter 3.4.2.2 --- Spectroscopic Properties of 94 --- p.61 / Chapter 3.4.2.3 --- Molecular Structure of [Ge(GeCl){CH(Pri2P=S)(Anth)}2Cl2C6H5CH3] (94) --- p.61 / Chapter 3.4.3.1 --- Synthesis of (9-Anthryl)(thiophosphinoyl)methanide Zirconium(IV) Complex [Zr{CH(Pri2P=S)(Anth)}2Cl2(THF) THF] (95) --- p.64 / Chapter 3.4.3.2 --- Spectroscopic Properties of 95 --- p.64 / Chapter 3.4.3.3 --- Molecular Structure of [Zr{CH(Pri2P=S)(Anth)}2Cl2(THF) THF] (95) --- p.65 / Chapter 3.4.3.4 --- Catalytic Study of [Zr{CH(Pri2P=S)(Anth)}2Cl2(THF) THF] (95)i --- p.68 / Chapter 3.5 --- Experimental Section --- p.69 / Chapter 3.6 --- References for Chapter 3 --- p.72
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_327000 |
| Date | January 2010 |
| Contributors | Ho, Ming Gong., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiii, 81 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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