The kinetics for the reaction of the oxidation of acetaldehyde by chromic acid in aqueous medium has been studied in an attempt to extend the present knowledge of oxidation by chromic acid. In particular, these experiments were undertaken in order to see if there are any similarities between this reaction and the oxidation of isopropyl alcohol in aqueous medium, which other investigators have studied.
The main runs were carried out at 25°, at an ionic strength of 0.3. The reaction was followed by the decrease in chromic acid concentration as determined with the Beckman Spectrophotometer. In all of the runs, the concentrations of acetaldehyde and H⁺ were in excess of the chromic acid concentrations.
It was found that the oxidation of acetaldehyde is first order in acetaldehyde and first order in HCrO₄⁻, (but not strictly first order in total chromic acid). The reaction is roughly second order in H⁺. Mn⁺² has an inhibitory effect upon the rate, as has been found in the isopropyl alcohol oxidation.
Because of the similarity in kinetic behavior between acetaldehyde and isopropyl alcohol, the mechanisms are probably very similar. This mechanism for acetaldehyde oxidation has been discussed in some detail. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/53499 |
| Date | January 1952 |
| Creators | McCarthy, Edward Raymond |
| Contributors | Chemistry |
| Publisher | Virginia Polytechnic Institute |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | en_US |
| Detected Language | English |
| Type | Thesis, Text |
| Format | 62 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 24990654 |
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