Pure chromium oxide trifluoride was prepared for the first time by reaction of CrO3 and ClF with subsequent multiple fluorine treatments at 120°c. On the basis of its infrared spectrum, the purple CrOF3 was assigned as a fluorine-bridged polymer with terminal oxygen groups. Chromium oxide trifluoride was found to be stable to 300°c, where it decomposes with the loss of oxygen to CrF3.
| Identifer | oai:union.ndltd.org:pdx.edu/oai:pdxscholar.library.pdx.edu:open_access_etds-4106 |
| Date | 01 January 1981 |
| Creators | Johnson, Bruce Michael |
| Publisher | PDXScholar |
| Source Sets | Portland State University |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | Dissertations and Theses |
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